Name: 地獄からのアロトロープ!// 私の一番危険な元素サンプル？ (Allotrope from Hell! // My most dangerous element sample?)
Uploaded: 2021-01-14T05:43:22.000Z
Duration: 10 min 10 s
Description: VoiceTubeの動画で発音を聞きながら英語表現を覚えよう！学べる英語：

The element in this video is actually one I have shown you before

but this time the element is in a much more aggressive form.

Some elements can combine their atoms in different ways.

This is called allotropes. Most famous for this

is perhaps the element carbon which can form into something as different

But this video is about phosphorus. In another video I have shown you the red

which is quite reactive but not nearly as much

at the white allotrope: white phosphorus.

This is a model of a white phosphorus molecule.

This shows the so-called ring strain. The bonds are very close

and at acute, sharp angles. They really don't like this

and want to break loose as illustrated here. So white phosphorus

is very reactive because it wants to break it bonds

and will for example react so intense with oxygen in the air

that it starts burning. I'll show it later.

that it turns into red phosphorus over time. The classic way of modeling

My sample of white phosphorus is not a high purity grade. Some of it

has degraded into red phosphorus giving it a yellow appearance.

This is often called yellow phosphorus. It's not a separate

allotrope - just a mixture of mostly white and some red.

but not without the mandatory safety instructions...

My point with this clip is: The only safe way to handle white phosphorus

The fire hazard is not the only major problem with white phosphorus.

fatal thallium - making this one of the most toxic elements.

The sample is stored under water to keep the oxygen in the air away from it.

Otherwise we would have a fire. White phosphorus

is practically insoluble in water but I still wouldn't drink this water.

Here it is: 12 g of white phosphorus Even when wet

it starts reacting only a few seconds after it is out of the water.

You should be able to see some fumes coming from the sample.

Don't breathe this. It turns into phosphoric acid with the moisture inside you.

A large sample like this will not ignite quickly unless the air is hot.

I still hold it above some water though because it is rather unpredictable.

Looks like this one is getting angrier. Let's move on...

so you better can see the waxy white phosphorus. High-purity white phosphorus

is almost glass clear but this is just a commercial-grade yellow sample.

Let's cut a small piece of and see if it will catch on fire.

Well, it is fuming a lot but not exactly an instant furious fire

but I have seen experiments where it took up to 15 minutes before a small sample

bigger is better with this unpure sample. I will now shut up

and show this clip uncut. Have patience and enjoy the show at the end.

Wauw, that worked well. What you couldn't see is how much smoke this fire created.

It is enough for the military to use it for smoke screens.

so I dare to go closer and show how much smoke even this small flame produces.

Imagine how much it was when the fire was really raging.

and phosphorus trioxide but also phosphine and elemental phosphorus.

The oxides react with moisture in the air so the end

products are a complicated mixture of polyphosphates.

This clearly is a dangerous element but actually it is debatable whether this

is my most dangerous element sample. Here are the fire diamonds for thallium,

cesium and white phosphorus. 4 is the worst - 0 is no problem.

in the blue square - which is about health - so even very short exposure to these two

is really bad. In the red square about flammability

white P also maxes out because it is pyrophoric

and in my opinion cesium should also max out here

because it will ignite in moist air. I am not sure about the score

of 3 here. Cesium scores the highest of these three

in the yellow square about instability because it reacts explosively with water

and generally is the most reactive metal.

So looking at the fire diamond alone, cesium seems at least

as dangerous as white phosphorus. Do you agree?

Okay - it is time to pack up and get this sample back to a dark place.

Let's finish off with something you can try at home.

Sparkling wine is fizzy - like soda. They even put a warning sign on the back of this:

But.. I'm gonna use that fizz for a classic trick.

Add mints and it should turn into a champagne geyser.

let's try it anyway. Take the cork off... and...

Okay, that's it for now. Thanks for all the subs

and remember to click like if you did like.