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  • Boiling point is something that we normally think of as a stable property of a substance.

  • But it really depends on what the pressure is around the substance,

  • so, for example, water only boils at 100 degrees Celsius, if the pressure is 1 atmosphere.

  • So if you reduce the pressure, then those water molecules that are going quite quickly

  • can easily escape from the water if there's no pressure pushing down on them.

  • So you can get water to boil at room temperature.

  • This is really boiling water.

  • The funny thing about boiling water at room temperature

  • is that it actually decreases the temperature of the water.

  • That's because all the fastest water molecules escape,

  • leaving only the slow ones behind.

  • We are refrigerating the water

  • Refrigerating the water, by boiling it.

  • Yes, yes

  • (Laughing)

  • That is a cool concept.

  • I know everyone's a big fan of liquid nitrogen, but I've never seen solid nitrogen.

  • So we used the same trick, pumping out the very fastest nitrogen molecules.

  • And eventually, that decreased the temperature enough that the nitrogen actually froze.

  • (Laughing)

  • I'm putting a thermocouple in there so we can measure the temperature of our liquid nitrogen.

  • And it reads...

  • Okay, so the temperature of our liquid nitrogen is about minus 196 Celsius.

  • Which is exactly what it should be.

  • And now we're going to evacuate the chamber.

  • We're gonna suck the air out of there.

  • you can see that the nitrogen is boiling

  • The temperature's dropping, minus 199, minus 200...

  • We're coming up on the triple point of nitrogen.

  • I don't know.

  • We're forming solid nitrogen.

  • The ice is actually getting sucked up by the reduced pressure up here,

  • and there is a higher pressure underneath the ice because the vacuum pump hasn't had a chance to work there.

  • I've never seen solid nitrogen before

  • After creating the solid nitrogen,

  • we poured it onto a water bath.

  • and we got the whole surface so cold that carbon dioxide actually condensed out of the atmosphere,

  • and we formed solid carbon dioxide, dry ice, on the surface of the water.

  • we have a solid piece of CO2

Boiling point is something that we normally think of as a stable property of a substance.

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B2 中上級

固体窒素を作る! (Making SOLID Nitrogen!)

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    林宜悉 に公開 2021 年 01 月 14 日
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