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  • - [Instructor] In this video,

  • we're gonna gain even more appreciation

  • for why the periodic table of elements is so useful.

  • And in particular, we're going to focus on

  • groups of the periodic table of elements.

  • When we talk about a group,

  • we're just talking about a column.

  • And as we'll see, even though the elements in a given column

  • might have very different atomic numbers,

  • they all have similar properties.

  • And the reason why they all have similar properties is,

  • in most cases, they have the same number

  • of valence electrons.

  • Remember, valence electrons are the reactive electrons,

  • the ones that might interact with other things.

  • And because elements with similar valence electrons

  • will have similar reactivities, they will form similar ions.

  • Similar ions.

  • And they will have similar roles.

  • Similar roles in ionic compounds.

  • Ionic compounds.

  • Now, for the sake of this video, I'm gonna focus most on

  • the extremes of the periodic table,

  • the groups at the left and the right,

  • because those are the closest to having a full outer shell,

  • either by losing electrons or by gaining electrons.

  • So just to remind ourselves,

  • what does it mean to have a full, full outer shell?

  • Well, in general, people will refer to the octet rule.

  • For our second, third, fourth, fifth, and on and on shells,

  • you're full when you have eight electrons.

  • Eight electrons.

  • The major exception to the octet rule is the first shell,

  • where it is full with two electrons.

  • So helium, even though it only has two electrons,

  • is very, very, very stable.

  • And the major data point that we have around this octet rule

  • are the group 18 elements right over here,

  • also known as the noble gasses.

  • They're known as the noble gasses

  • because they're very unreactive, they're very content,

  • they don't wanna mess around with anyone else.

  • And that's because all of the noble gasses

  • have full outer shells.

  • Helium's outer shell is the first shell and it's full.

  • Neon's outer shell's the second shell, it's full.

  • Argon's outer shell is the third shell and it's full,

  • and so on and so forth.

  • Now, if we go one group to the left of the noble gasses,

  • we get to the halogens.

  • Now, the halogens have seven valence electrons.

  • So you can imagine, they're only one electron away from

  • having an electron configuration like the noble gas

  • to the right of each of them.

  • So these halogens right over here,

  • these really like to attract electrons

  • to form a negative ion or an anion.

  • So you'll oftentimes see fluorine as a fluoride anion,

  • so it has a negative one charge.

  • Or you'll also see chlorine with a negative one charge

  • as the chloride anion.

  • And I could go on and on.

  • You'll often see iodine gain an electron

  • and have a negative one charge.

  • If you go one step to the left, the oxygen group,

  • oxygen, sulfur, and on and on,

  • these elements have six valence electrons.

  • So it's still easier for them to have a full outer shell

  • by gaining two electrons than by losing six electrons.

  • So these elements also like to attract electrons.

  • So you can see oxygen as an oxide anion.

  • It has gained two electrons,

  • it's swiped it from somebody else.

  • Sulfur as a sulfide anion.

  • Now, if you go to the other extreme of the periodic table,

  • if you look at group one elements,

  • they have one valence electron.

  • And especially the ones that you look,

  • and you see in red here,

  • which are known as the alkali metals,

  • it's much easier for them to lose an electron

  • to have a full outer shell

  • than for them to gain seven electrons.

  • The reason why hydrogen's a bit of an exception is

  • it doesn't have to gain seven electrons

  • to have a full outer shell, it has to gain one.

  • So hydrogen could lose one,

  • and essentially have no electrons,

  • or it could gain one electron

  • and it would have a full outer shell like helium.

  • But when we think about ionic compounds,

  • these alkali metals are really

  • some of the most interesting participants.

  • Because as you can imagine, for them to get stable,

  • they wanna give away an electron.

  • So you're very likely to see them

  • having given away an electron

  • and having a positive one charge.

  • So you'll oftentimes see a lithium ion

  • with a positive one charge,

  • a sodium ion with a positive one charge,

  • a potassium ion with a positive one charge.

  • And that's, in general,

  • true of all of these group one elements.

  • Now, what about these group two elements,

  • also known as the alkaline earth metals?

  • Well, once again, it's easier for them to lose two electrons

  • than for them to gain six and have a full outer shell.

  • So, you'll typically see beryllium

  • having a positive two charge.

  • It would have lost those two electrons.

  • Magnesium as having a positive two charge.

  • Calcium as having a positive two charge.

  • Now, given that, how would you expect things on the left

  • and things on the right to form ionic compounds?

  • So you might guess, if you have an alkali metal

  • in the presence of a halogen,

  • things could get very reactive.

  • In fact, things will get very reactive

  • because these wanna give away electron,

  • these wanna take electron.

  • And that's what will happen.

  • The electrons will leave the group one elements

  • and then they will go to the halogen.

  • And in the process it might release a lot of energy,

  • but what you'd be left with is an ionic compound.

  • For example, lithium loses a electron

  • and has a positive one charge.

  • That positive ion would be very attracted to

  • a chlorine anion that has just gained an electron.

  • Maybe it's the same electron,

  • or it swiped that electron from another lithium atom.

  • And so these two things would be attracted

  • and they could form lithium chloride.

  • And all of these alkali metals could play that same role

  • in this ionic compound as lithium.

  • So it's also typical to see sodium chloride.

  • That is table salt.

  • It's also typical to see potassium chloride.

  • So on and so forth.

  • And on the other hand, fluorine or bromine or iodine

  • can play a similar role as chlorine.

  • So you could see something like sodium iodide

  • or potassium iodide.

  • Once again, the alkali metal would have lost an electron,

  • the halogen would have gained an electron,

  • and then they're attracted to each other

  • in forming these ionic compounds.

  • What kind of ionic compounds might be formed

  • with these group two elements?

  • Let's take calcium, for example.

  • It's not unreasonable for calcium to lose two electrons

  • to have a stable outer shell,

  • to have an electron configuration like argon.

  • So if it loses two electrons it has a positive two charge.

  • And you could imagine, those two electrons get lost

  • to two different iodine atoms.

  • So each of them have a negative one charge, so times two,

  • and then what type of ionic compound could they form?

  • Well, you could have one calcium and then two iodines.

  • So calcium iodide is actually

  • an ionic compound you would see.

  • It has a neutral charge overall

  • because calcium has a positive two charge

  • and each of the iodines have a negative one charge,

  • but then you have two of them, so it is neutral overall.

  • What might calcium do with oxygen?

  • Well, calcium likes to lose two electrons,

  • oxygen likes to gain two electrons,

  • so you could see something like calcium oxide.

  • So I will leave you there.

  • The big picture here is, the column in which an element is

  • tells you a lot about its reactivity

  • because it tells you in general

  • how many valence electrons it has.

  • And atoms are most stable when they have a full outer shell

  • and so that helps you predict, hey, is it easier for them

  • to lose electrons and form a positive ion

  • or gain electrons and form a negative ion?

  • And then from that, you could make predictions

  • as to the types of ionic compounds

  • that could be formed with the different elements.

- [Instructor] In this video,

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原子価電子とイオン性化合物|AP化学|カーンアカデミー (Valence electrons and ionic compounds | AP Chemistry | Khan Academy)

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    林宜悉 に公開 2021 年 01 月 14 日
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