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  • - [Instructor] In this video we're gonna try to get

  • more practice constructing Lewis diagrams.

  • And we're gonna try to do that for a cyanide anion.

  • So this is interesting.

  • This is the first time we're constructing

  • a Lewis diagram for an ion.

  • So pause this video and see if you can have a go at that.

  • All right, now let's do this together.

  • So we've already seen in many videos,

  • the first step is to essentially count

  • the total valence electrons that we're dealing with.

  • And the reason why we do that is to make sure

  • that we're allocating all the valence electrons.

  • To help us there

  • we can look at a periodic table of elements.

  • You might already know that carbon has

  • one, two, three, four valence electrons

  • in that second shell, it's in the second period,

  • so you have four valence electrons from carbon.

  • Nitrogen has one, two, three, four, five valence electrons

  • in its second shell, it's in that second period.

  • And so the valence electrons from a neutral carbon

  • and a neutral nitrogen-free atom

  • would be a total of nine valence electrons.

  • But we are not done yet.

  • Because this is not a neutral molecule.

  • We have a negative charge here.

  • It is an anion, it has a negative one charge.

  • And so because of that negative one

  • we can think about it having an extra valence electron.

  • So let's add a valence electron here.

  • Why do we do it?

  • Because of this negative charge.

  • So we're dealing with a total of 10 valence electrons.

  • Now, the next step is to try to draw single bonds.

  • Try single bonds, and identify a central atom.

  • Now, we only have two atoms here,

  • so really neither feels central,

  • so let me just put a carbon

  • and a nitrogen next to each other here.

  • And then let me draw one single bond.

  • So by drawing that one single bond

  • I have now accounted for two valence electrons.

  • So now I am left with eight valence electrons,

  • and so that's the next step,

  • allocate remaining valence electrons,

  • allocate valence electrons.

  • So let me start with the more electronegative.

  • Let's try to get nitrogen to eight.

  • It already has two.

  • So let's give it three more lone pairs.

  • So we have two, four, six, eight.

  • So I have just used up six

  • of these remaining valence electrons, six, so minus six,

  • so I have two left to allocate.

  • So let me give carbon two valence electrons, like that.

  • And there I have used up all of my,

  • all of my valence electrons.

  • Now let's see how happy everyone is.

  • Nitrogen has eight valence electrons hanging around,

  • two, four, six, eight.

  • But carbon only has four, two and four.

  • So this is where we think about

  • whether we would want to have some extra bonds,

  • extra bonds, or higher-order bonds.

  • So how can we give carbon more valence electrons?

  • Well, what we could do is

  • we could take some of these lone pairs around nitrogen

  • and then use them, turn this single covalent bond

  • into a higher-order bond.

  • So let's see, if we were to take these two

  • and turn it into another covalent bond,

  • what is going to happen?

  • Let me erase all of these,

  • and then I'll just draw another covalent bond.

  • So nitrogen still has eight electrons hanging around.

  • Carbon now has six.

  • So maybe we can do that again.

  • So let me erase these two characters.

  • Let me erase these two characters

  • and make another covalent bond out of them.

  • So let me make a covalent bond out of them.

  • And so now what's going on?

  • Carbon has two, four, six, eight

  • valence electrons hanging around.

  • Nitrogen has two, four, six, eight

  • valence electrons hanging around.

  • So this is looking pretty good.

  • But are we done yet?

  • The simple answer is no.

  • We still haven't represented this negative charge

  • in our Lewis diagram.

  • The way that we would do that is say hey,

  • this entire molecule, you put brackets around it,

  • has a negative charge.

  • And now we're done.

  • We've allocated all of our valence electrons,

  • we have our octet rule on all of our atoms

  • that are not hydrogen, there's no hydrogen here,

  • and we're showing that this indeed is an anion,

  • and now we are done.

- [Instructor] In this video we're gonna try to get

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B2 中上級

作業例。シアン化物イオン(CN-)のルイス線図|AP化学|カーンアカデミー (Worked example: Lewis diagram of the cyanide ion (CN⁻) | AP Chemistry | Khan Academy)

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    林宜悉 に公開 2021 年 01 月 14 日
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